Study of Structural Stability of Thin Films of CH3NH3PbI3 Hybrid Perovskite under Ambient Conditions

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Abstract

Hybrid organic-inorganic perovskite materials are of current interest as promising light-harvesting materials for photovoltaics. However, the main problem of their industrial implementation is the stability in various temperature and humidity conditions. The change in the crystal structure of hybrid perovskite thin films under ambient conditions was studied using X-ray diffraction. In particular, during the degradation of films, the formation of a monohydrate as an intermediate phase was detected. Also, X-ray diffraction data indicated layer-by-layer degradation of the films.

About the authors

T. Y. Zelenyak

Joint Institute for Nuclear Research

Author for correspondence.
Email: tatyana.zelenyak@bk.ru
Russian Federation, Dubna, Moscow Oblast, 141980

A. S. Doroshkevich

Joint Institute for Nuclear Research

Email: tatyana.zelenyak@bk.ru
Russian Federation, Dubna, Moscow Oblast, 141980

V. V. Kriger

Joint Institute for Nuclear Research

Email: tatyana.zelenyak@bk.ru
Russian Federation, Dubna, Moscow Oblast, 141980

T. N. Vershinina

Joint Institute for Nuclear Research

Email: tatyana.zelenyak@bk.ru
Russian Federation, Dubna, Moscow Oblast, 141980

T. V. Tropin

Joint Institute for Nuclear Research

Email: tatyana.zelenyak@bk.ru
Russian Federation, Dubna, Moscow Oblast, 141980

M. V. Avdeev

Joint Institute for Nuclear Research; State University Dubna

Email: avd@nf.jinr.ru
Russian Federation, Dubna, Moscow Oblast, 141980; Dubna, Moscow Oblast, 141982

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