Enviar artigo por via de e-mail Influence of substitute in the ligand and counterion on the properties of heptanuclear iron complex
- Autores: Batueva Е.Е.1, Sharipova A.R.2, Frolova Е.N.2, Savostina L.I.1,2, Bazan L.V.2, Cherosov M.A.1, Batulin R.G.1, Turanova O.A.2, Turanov A.N.2
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Afiliações:
- Kazan Federal University
- Federal Research Center Kazan Scientific Center of Russian Academy of Sciences
- Edição: Volume 88, Nº 7 (2024)
- Páginas: 1135-1140
- Seção: Spin physics, spin chemistry and spin technologies
- URL: https://rjpbr.com/0367-6765/article/view/676763
- DOI: https://doi.org/10.31857/S0367676524070213
- EDN: https://elibrary.ru/OZQSZY
- ID: 676763
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Resumo
New heptanuclear mixed-valence iron complexes with pentadentate ligands have been synthesized, and their magnetic properties have been studied. It has been found that the presence of thiocyanate anions leads to the emergence of spin-crossover properties by magnetometry and EPR methods. The insertion of long alkoxy chains into the molecule leads to thermotropic liquid crystalline properties and enhanced cooperative magnetic properties.
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Sobre autores
Е. Batueva
Kazan Federal University
Email: sasha_turanov@rambler.ru
Rússia, Kazan
A. Sharipova
Federal Research Center Kazan Scientific Center of Russian Academy of Sciences
Email: sasha_turanov@rambler.ru
Zavoisky Physical-Technical Institute
Rússia, KazanЕ. Frolova
Federal Research Center Kazan Scientific Center of Russian Academy of Sciences
Email: sasha_turanov@rambler.ru
Zavoisky Physical-Technical Institute
Rússia, KazanL. Savostina
Kazan Federal University; Federal Research Center Kazan Scientific Center of Russian Academy of Sciences
Email: sasha_turanov@rambler.ru
Zavoisky Physical-Technical Institute
Rússia, Kazan; KazanL. Bazan
Federal Research Center Kazan Scientific Center of Russian Academy of Sciences
Email: sasha_turanov@rambler.ru
Zavoisky Physical-Technical Institute
Rússia, KazanM. Cherosov
Kazan Federal University
Email: sasha_turanov@rambler.ru
Rússia, Kazan
R. Batulin
Kazan Federal University
Email: sasha_turanov@rambler.ru
Rússia, Kazan
O. Turanova
Federal Research Center Kazan Scientific Center of Russian Academy of Sciences
Email: sasha_turanov@rambler.ru
Zavoisky Physical-Technical Institute
Rússia, KazanA. Turanov
Federal Research Center Kazan Scientific Center of Russian Academy of Sciences
Autor responsável pela correspondência
Email: sasha_turanov@rambler.ru
Zavoisky Physical-Technical Institute
Rússia, KazanBibliografia
- Магомедов К.Э., Омельянчик А.С., Воронцов С.А. и др. // Изв. РАН. Сер. физ. 2023. Т. 87. № 6. С. 819; Magomedov K.E., Omelyanchik A.S., Vorontsov S.A. et al. // Bull. Russ. Acad. Sci. Phys. 2023. V. 87. No. 6. P. 720.
- Хлюстова А.В., Шипко М.Н., Степович М.А. и др. // Изв. РАН. Сер. физ. 2023. Т. 87. № 10. С. 1517; Khlyustova A.V., Shipko M.N., Stepovich M.A. et al. // Bull. Russ. Acad. Sci. Phys. 2023. V. 87. No. 10. P. 1549.
- Кафеева Д.А., Куршанов Д.А., Дубовик А.Ю. // Изв. РАН. Сер. физ. 2023. Т. 87. № 6. С. 801; Kafeeva D.A., Kurshanov D.A., Dubavik, A.Y. // Bull. Russ. Acad. Sci. Phys. 2023. 87. No. 6. P. 705.
- Макеев М.Ю., Мамонова М.В. // Изв. РАН. Сер. физ. 2023. Т. 87. № 4. С. 493; Makeev M.Y., Mamonova M.V. // Bull. Russ. Acad. Sci. Phys. 2023. V. 87. No. 4. P. 427.
- Salitros I., Madhu N.T., Boca R. et al. // Monatsh fur Chemie. 2009. V. 140. P. 695.
- Овчинников И.В., Иванова Т.А., Туранова О.А. и др. // Коорд. химия. 2013. Т. 39. № 8. С. 502; Ovchinnikov I.V., Ivanova T.A., Turanova O.A. et al. // Rus. J. Coord. Chem. 2013. V. 39. No. 8. P. 598.
- Boca R., Nemec I., Salitros I. et al. // Pure Appl. Chem. 2009. V. 81. No. 8. P. 1357.
- Boca R., Salitros I., Kozisek J. et al. // Dalton Trans. 2010. V. 39. No 9. P. 2198.
- Salitros I., Boca R., Herchel R. et al. // Inorg. Chem. 2012. V. 51. No 23. P. 12755.
- Liu J.L., Ji X.Y., Xue J.P. et al. // Crys. Growth Des. 2022. V. 22. No. 8. P. 5092.
- Bleuzen A., Marvaud V., Mathoniere C. et al. // Inorg. Chem. 2009. V. 48. No. 8. P. 3453.
- Shan Y., Zhang G., Yin W. et al. // Bull. Chem. Soc. Japan. 2022. V. 95. No 2. P. 230.
- Фролова Е.Н., Иванова Т.А., Туранова О.А. и др. // Журн. неорг. химии. 2018. Т. 63. № 8. С. 974.; Frolova E.N., Ivanova T.A., Turanova O.A. et al. // Russ. J. Inorg. Chem. 2018. V. 63. No. 8. P. 1012.
- Туранова О.А., Иванова Г.И., Гафиятуллин Л.Г. и др. // Журн. общ. химии. 2014. Т. 84. № 11. С. 1878; Turanova O.A., Ivanova G.I., Gafiyatullin L.G. et al. // Russ. J. Gen. Chem. 2014. V. 84. No. 11. P. 2174.
- Matsumoto N., Ohta S., Yoshimura C. et al. // J. Chem. Soc. Dalton Trans. 1985. V. 12. P. 2575.
- Gembicky M., Boca R., Renz F. // Inorg. Chem. Commun. 2000. V. 3. No. 11. P. 662.
- Dierking I. Textures of liquid crystals. Hoboken: John Wiley & Sons, 2006. 230 p.
- Neese F. // WIREs Comput. Mol. Sci. 2012. V. 2. No. 1. P. 73.
- Neese F. // WIREs Comput. Mol. Sci. 2022. V. 12. No. 5. Art. No. e1606.
- Stoll S., Schweiger A. // J. Magn. Reson. 2006. V. 178. No. 1. P. 42.
- Вульфсон С.Г. Молекулярная магнетохимия. М.: Наука, 1991. 260 с.
- Boca R., Salitros I. // Chem. Papers. 2008. V. 62. No. 6. P. 575.
- Иванова Т.А., Мингалиева Л.В., Овчинников И.В. и др. // Журн. общ. химии. 2016. Т. 86. № 7. С. 1170; Ivanova T.A., Mingalieva L.V., Ovchinnikov I.V. et al. // Russ. J. Gen. Chem. 2016. V. 86. No. 7. P. 1647.
- Иванова Т.А., Овчинников И.В., Гильмутдинов И.Ф. и др. // ФТТ. 2016. Т. 58. № 2. С. 273.; Ivanova T.A., Ovchinnikov I.V., Gil’mutdinov I.F. et al. // Phys. Solid State. 2016. V. 58. No. 2. P. 280.
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