Effect of the Counterion of Styrenesulfonic and Maleic Acid Copolymer on the Properties of Its Complexes with Polyvinyl Alcohol

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Abstract

In this work, the interaction of a copolymer of styrene sulfonic and maleic acids in acidic and salt forms with polyvinyl alcohol in a wide concentration range was studied using light scattering and viscometry methods, and it was shown that the nature of the copolymer counterion has a significant effect on the properties of the resulting interpolymer complexes. In dilute solutions, polyvinyl alcohol interacts only with the salt form of the copolymer. In semi-dilute solutions, both forms of the copolymer interact with polyvinyl alcohol, but water-soluble complexes for all ratios of the copolymer and polyvinyl alcohol are formed only with the participation of the acid form of the copolymer.

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About the authors

D. E. Ochenkov

M. V. Lomonosov Moscow State University

Email: pyshkina@gmail.com
Russian Federation, Moscow, 119992

S. A. Pantsernaya

M. V. Lomonosov Moscow State University

Email: pyshkina@gmail.com
Russian Federation, Moscow, 119992

A. A. Neudakhina

M. V. Lomonosov Moscow State University

Email: pyshkina@gmail.com
Russian Federation, Moscow, 119992

R. V. Grossman

M. V. Lomonosov Moscow State University

Email: pyshkina@gmail.com
Russian Federation, Moscow, 119992

O. A. Pyshkina

M. V. Lomonosov Moscow State University

Author for correspondence.
Email: pyshkina@gmail.com
Russian Federation, Moscow, 119992

V. G. Sergeyev

M. V. Lomonosov Moscow State University

Email: pyshkina@gmail.com
Russian Federation, Moscow, 119992

E. A. Litmanovich

M. V. Lomonosov Moscow State University

Email: pyshkina@gmail.com
Russian Federation, Moscow, 119992

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Supplementary files

Supplementary Files
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2. Fig. 1. Dependence of experimental and calculated additive values of the logarithm of dynamic viscosity on the composition of mixtures of PVS–PSMNA. The dotted lines correspond to the calculated additive dependencies, while the solid lines are based on experimental data. The total polymer concentration is 10% by weight.

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3. Fig. 2. The dependences of the compositions of the upper and lower phases on the composition of the mixture of PVS–PSMNA.

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4. Fig. 3. Static light scattering data for solutions of PSMN, PVS and their mixtures.

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5. 4. The dependence of the average molecular weight of the mixtures of PVS–PSMN (a) and PVS–PSMNA (b, curve 1) on the mass fraction of the copolymer. For comparison, the calculated additive dependence in the absence of interactions is shown (curve 2).

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6. 5. Distribution of the scattering amplitude of PVS, PSMN and their mixtures of compositions w = 0.2–0.8 by hydrodynamic radii. The scattering angle is 90°, 25°C.

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7. 6. Dependence of experimental and calculated additive values of the logarithm of dynamic viscosity on the composition of mixtures of PVS–PSMN. The lines correspond to the calculated additive dependencies, the points correspond to the experimental data. The total polymer concentration is 10% by weight.

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8. Fig. 7. Schematic representation of the PVS–PSMN complex, dotted lines indicate hydrogen bonds.

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9. Fig. 8. Dependence of the logarithm of viscosity on the inverse temperature for various compositions [wmas% (WSMNA)] (a) and [w mass% (WSMN)] (b). The total polymer concentration is 10 wt%.

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10. 9. The dependence of enthalpy (a) and entropy (b) of viscous flow activation on the composition of the polymer solution.

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11. 10. Dependence of the logarithm of the specific viscosity of PVS (1), PSM (2) and their mixtures with the mass fraction of the copolymer w = 0.2 (3) on the logarithm of the concentration. The arrows show the boundaries of concentration regimes.

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12. 11. Schematic representation of the structuring of a PVA solution in the crossover region in the presence of copolymer chains.

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