Oxidative Dehydrogenation of Ethane on Oxide-Supported Vanadium Phosphorus Oxide Catalysts

A. A. Malygin; Малыгин А. А.; A. B. Yaroslavtsev; Ярославцев А. Б.; N. A. Zhilyaeva; Жиляева Н. А.; V. I. Elizarova; Елизарова В. И.; E. Yu. Mironova; Миронова Е. Ю.; A. A. Malkov; Малков А. А.; I. S. Bodalyov; Бодалёв И. С.

doi:10.31857/S0044457X22600918

Oxidative Dehydrogenation of Ethane on Oxide-Supported Vanadium Phosphorus Oxide Catalysts

Authors: Malygin A.A.¹, Yaroslavtsev A.B.²^,3, Zhilyaeva N.A.², Elizarova V.I.², Mironova E.Y.², Malkov A.A.¹, Bodalyov I.S.¹
Affiliations:
1. Saint Petersburg State Institute of Technology
2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
Issue: Vol 68, No 1 (2023)
Pages: 96-104
Section: НЕОРГАНИЧЕСКИЕ МАТЕРИАЛЫ И НАНОМАТЕРИАЛЫ
URL: https://rjpbr.com/0044-457X/article/view/665333
DOI: https://doi.org/10.31857/S0044457X22600918
EDN: https://elibrary.ru/GVDJNL
ID: 665333

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

Comparative results of studying the oxidative dehydrogenation of ethane (ODE) on catalytic vanadium-phosphorus oxide systems deposited by the molecular layering method on the surface of oxide supports (Al2O3, SiO2) have been presented. It has been found that the highest activity in ODE and selectivity for ethylene are exhibited by vanadium-phosphorus-containing catalysts. The influence of the acidity of catalytic systems on the activity and selectivity of the process has been revealed. The selectivity of the ODE process for ethylene reaches 90%. An increase in the oxygen concentration in the initial mixture from 3.5 to 20% leads mainly to a decrease in the selectivity of the ODE process with respect to the ethylene yield.

Keywords

oxidative dehydrogenation, ethane, ethylene, vanadium phosphorus oxide systems, molecular layering

References

Lopez-Nieto J.M., Botella P., Vazquez M.I. et al. // Chem. Commun. 2002. V. 17. P. 1906. https://doi.org/10.1039/B204037A
Fattahi M., Kazemeini M., Khorasheh F. et al. // Chem. Eng. Technol. 2013. V. 36. № 10. P. 1691. https://doi.org/10.1002/ceat.201300148
Gärtner C.A., van Veen A.C., Lercher J.A. // ChemCatChem. 2013. V. 5. P. 3196. https://doi.org/10.1002/cctc.201200966
Heracleous E., Lemonidou A.A. // J. Catal. 2006. V. 237. № 1. P. 162. https://doi.org/10.1016/j.jcat.2005.11.002
Lazareva E.V., Bondareva V.M., Svintsitskiy D.A. et al. // Catal. Today. 2021. V. 361. P. 50. https://doi.org/10.1016/j.cattod.2019.12.029
Chu B., Truter L., Nijhuis T.A. et al. // Appl. Catal. A. 2015. V. 498. P. 99. https://doi.org/10.1016/j.apcata.2015.03.039
Fazlinezhad A., Naeimi A., Yasari E. // Chem. Eng. Res. Des. 2019. V. 146. P. 427. https://doi.org/10.1016/j.cherd.2019.04.028
Mishanin I.I., Bogdan V.I. // Mendeleev Commun. 2019. V. 29. P. 455. https://doi.org/10.1016/j.mencom.2019.07.034
Kucherov A.V., Finashina E.D., Kustov L.M. et al. // Mendeleev Commun. 2020. V. 30. P. 657. https://doi.org/10.1016/j.mencom.2020.09.035
Chu B., An H., Chen X. et al. // Appl. Catal. A. 2016. V. 524. P. 56. https://doi.org/10.1016/j.apcata.2016.05.026
Ermilova M., Kucherov A., Orekhova N. et al. // Chem. Eng. Process. 2018. V. 126. P. 150. https://doi.org/10.1016/j.cep.2018.02.011
Savova B., Loridant S., Filkova D. et al. // Appl. Catal. A. 2010. V. 390. P. 148. https://doi.org/10.1016/j.apcata.2010.10.004
Solsona B., Concepciyn P., Demicol B. et al. // J. Catal. 2012. V. 295. P. 104. https://doi.org/10.1016/j.jcat.2012.07.028
Zhu H., Dong H., Laveille P. et al. // Catal. Today. 2014. V. 228. P. 58. https://doi.org/10.1016/j.cattod.2013.11.061
Sanchis R., Delgado D., Agouram S. et al. // Appl. Catal. A. 2017. V. 536. P. 18. https://doi.org/10.1016/j.apcata.2017.02.012
Boukhlouf H., Barama A., Benrabaa R. et al. // C.R. Chim. 2017. V. 20. P. 30. https://doi.org/10.1016/j.crci.2016.02.016
Zhang Z., Ding J., Chai R. et al. // Appl. Catal. A. 2018. V. 550. P. 151. https://doi.org/10.1016/j.apcata.2017.11.005
Solsona B., Zazhigalov V.A., López Nieto J.M. et al. // Appl. Catal. A. 2003. V. 249. P. 81. https://doi.org/10.1016/S0926-860X(03)00178-9
Lisi L., Ruoppolo G., Casaletto M.P. et al. // J. Mol. Catal. A: Chem. 2005. V. 232. P. 127. https://doi.org/10.1016/j.molcata.2005.01.035
Vedrine J.C., Hutchings G.J., Kiely C.J. // Catal. Today. 2013. V. 217. P. 57. https://doi.org/10.1016/j.cattod.2013.01.004
Ivars-Barceló F., Hutchings G.J., Bartley J.K. et al. // J. Catal. 2017. V. 354. P. 236. https://doi.org/10.1016/j.jcat.2017.08.020
Haddad N., Bordes-Richard E., Barama A. // Catal. Today. 2009. V. 142. P. 215. https://doi.org/10.1016/j.cattod.2008.09.015
Mikhailovskii S.V., Chernov A.S., Mironova E.Yu. et al. // Russ. J. Appl. Chem. 2014. V. 87. № 1. P. 23. [Михайловский С.В., Чернов А.С., Миронова Е.Ю. и др. // Журн. прикл. химии. 2014. Т. 87. № 1. С. 26.]https://doi.org/10.1134/S1070427214010030
Sosnov E.A., Malkov A.A., Malygin A.A. // Russ. J. Appl. Chem. 2021. V. 94. P. 1189. https://doi.org/10.1134/S1070427221090020
Дроздов Е.О., Дубровенский С.Д., Малыгин А.А. // Журн. общ. химии. 2020. Т. 90. № 5. С. 795. https://doi.org/10.31857/S0044460X20050212
Захарова Н.В., Аккулева К.Т., Малыгин А.А. // Журн. общ. химии. 2020. Т. 90. № 9. С. 1414. https://doi.org/10.31857/S0044460X20090139
Zhilyaeva N.A., Ermilova M.M., Orekhova N.V. et al. // Inorg. Mater. 2018. V. 54. № 11. P. 1136. [Жиляева Н.А., Ермилова М.М., Орехова Н.В. и др. // Неорган. материалы. 2018. Т. 54. № 11. С. 1202.]https://doi.org/10.1134/S002016851811016X
Mikhailovskii S.V., Zhilyaeva N.A., Obletsova A.A. et al. // Russ. J. Appl. Chem. 2016. V. 89. № 1. P. 34. [Михайловский С.В., Жиляева Н.А., Облецова А.А. и др. // Журн. прикл. химии. 2016. Т. 89. № 1. С. 37.]https://doi.org/10.1134/S1070427216010055
Wang Sh., Murata K., Hayakawa T. et al. // Stud. Surf. Sci. Catal. 2000. V. 130. P. 1829. https://doi.org/10.1016/S0167-2991(00)80467-X
Peng X., Zhu J., Yao L. et al. // J. Energy Chem. 2013. V. 22. P. 653. https://doi.org/10.1016/S2095-4956(13)60086-8
Botavina M.A., Martra G., Agafonov Yu.A. et al. // Appl. Catal. A. 2008. V. 347. P. 126. https://doi.org/10.1016/j.apcata.2008.05.037
Ates A., Hardacre Ch., Goguet A. // Appl. Catal. A. 2012. V. 441–442. P. 30. https://doi.org/10.1016/j.apcata.2012.06.038
Zhu J., Qin S., Ren S. et al. // Catal. Today. 2009. V. 148. P. 310. https://doi.org/10.1016/j.cattod.2009.07.074
Casaletto M.P., Lisi L., Mattogno G. et al. // Surf. Interface Anal. 2004. V. 36. P. 737. https://doi.org/10.1002/sia.1751
Le Bars J., Vedrine J.C., Auroux A. et al. // Appl. Catal. A. 1992. V. 88. № 2. P. 179. https://doi.org/10.1016/0926-860X(92)80214-W
Grabowski R., Słoczynski J. // Chem. Eng. Process. 2005. V. 44. P. 1082. https://doi.org/10.1016/j.cep.2005.03.002
Klisinska A., Samson K., Gressel I. et al. // Appl. Catal. A. 2006. V. 309. P. 10. https://doi.org/10.1016/j.apcata.2006.04.028
Zhilyaeva N.A., Mironova E.Yu., Ermilova M.M. et al. // Sep. Purif. Technol. 2018. V. 195. P. 170. https://doi.org/10.1016/j.seppur.2017.12.011
Volkov A.O., Golubenko D.V., Yaroslavtsev A.B. // Sep. Purif. Technol. 2021. V. 254. P. 117562. https://doi.org/10.1016/j.seppur.2020.117562
Nguyen T.-D., Do T.-O. // Langmuir. 2009. V. 25. № 9. P. 5322. https://doi.org/10.1021/la804073a
Uskokovic V. // Phys. Chem. Chem. Phys. 2020. V. 22. P. 5531. https://doi.org/10.1039/C9CP06529F
Harju P.H., Pasek E.A. Pat. 4374756 US: Filed 09.09.1981: Granted 22.02.1983
Cavani F., Trifiro F. // ChemInform. 1994. V. 25. № 34. https://doi.org/10.1002/chin.199434086