Epoxidation of Olefins in the Presence of Molybdenum Catalysts based on Porous Aromatic Frameworks

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Abstract

A porous aromatic framework, namely PAF-30, was structurally modified by the introduction of complexing groups based on dipyridylamine, dipicolylamine, and acetylacetone. The materials synthesized in this manner were used as supports of molybdenum catalysts for epoxidation: PAF-30-dpa-Mo, PAF-30-dpcl-Mo, and PAF-30-AA-Mo. All the materials were examined by various analytic methods, such as IR spectroscopy, low-temperature nitrogen adsorption/desorption, X-ray photoelectron spectroscopy, elemental analysis, and transmission electron microscopy. The catalytic activity was tested in epoxidation of cyclohexene, 1-hexene, 1-octene, and styrene. The reusability of the catalysts was assessed using the case of cyclohexene epoxidation.

About the authors

V. A. Yarchak

Faculty of Chemistry, Lomonosov Moscow State University

Email: yarchakvika@gmail.com
119991, Moscow, Russia

L. A. Kulikov

Faculty of Chemistry, Lomonosov Moscow State University

Email: petrochem@ips.ac.ru
119991, Moscow, Russia

A. L. Maksimov

Faculty of Chemistry, Lomonosov Moscow State University; Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences

Email: petrochem@ips.ac.ru
119991, Moscow, Russia; 119991, Moscow, Russia

E. A. Karakhanov

Faculty of Chemistry, Lomonosov Moscow State University

Author for correspondence.
Email: petrochem@ips.ac.ru
119991, Moscow, Russia

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