Sintez zhidkikh uglevodorodov iz SO2 v odnu stadiyu s ispol'zovaniem gibridnykh sokristallizovannykh tseolitnykh struktur

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Abstract

Проведено исследование реакции конверсии СО2 в жидкие углеводороды (Emission to Liquid) в одну стадию при температуре 340°С и давлении 10.0 МПа. Катализатор представлял собой послойно загруженные оксидный медь-цинковый компонент тандемного катализатора, отвечающий за синтез метанола из СО2, и цеолитный компонент катализатора, отвечающий за конверсию метанола в жидкие углеводороды. Изучено влияние структуры гибридного сокристаллизованного цеолита в составе цеолитного компонента на выход и углеводородный состав жидких продуктов. Показано, что именно текстурные свойства цеолитного компонента определяют состав получаемых жидких углеводородов. Использование гибридных сокристаллических структур MFI/MEL и MFI/MCM-41 с большим количеством мезопор существенно увеличивают содержание ароматических соединений в составе жидких углеводородов не только за счет снижения диффузионных ограничений отвода продукта из пор цеолита, но и за счет активации вторичных реакций ароматизации в мезопорах катализатора.

About the authors

M. V. Magomedova

Институт нефтехимического синтеза им. А.В. Топчиева РАН

A. V. Starozhitskaya

Институт нефтехимического синтеза им. А.В. Топчиева РАН

Email: av-star@ips.ac.ru

E. G. Galanova

Институт нефтехимического синтеза им. А.В. Топчиева РАН

D. V. Matevosyan

Институт нефтехимического синтеза им. А.В. Топчиева РАН

S. V. Egazar'yants

Московский государственный университет имени М.В. Ломоносова

A. L. Maksimov

Институт нефтехимического синтеза им. А.В. Топчиева РАН

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