SINGLE-, DOUBLE- AND MULTI-WALLED CARBON NANOTUBES AS ELECTRICALLY CONDUCTIVE ADDITIVES IN LITHIUM-ION BATTERY CATHODES

A. V. Babkin; Бабкин А. В.; A. V. Kubarkov; Кубарьков А. В.; O. A. Drozhzhin; Дрожжин О. А.; S. A. Urvanov; Урванов С. А.; I. S. Filimonenkov; Филимоненков И. С.; A. G. Tkachev; Ткачев А. Г.; V. Z. Mordkovich; Мордкович В. З.; V. G. Sergeyev; Сергеев В. Г.; E. V. Antipov; Антипов Е. В.

doi:10.31857/S268695352260074X

SINGLE-, DOUBLE- AND MULTI-WALLED CARBON NANOTUBES AS ELECTRICALLY CONDUCTIVE ADDITIVES IN LITHIUM-ION BATTERY CATHODES

Authors: Babkin A.V.¹, Kubarkov A.V.¹, Drozhzhin O.A.¹, Urvanov S.A.², Filimonenkov I.S.², Tkachev A.G.³, Mordkovich V.Z.², Sergeyev V.G.¹, Antipov E.V.¹^,4
Affiliations:
1. Department of Chemistry, Lomonosov Moscow State University
2. Technological Institute for Superhard and Novel Carbon Materials
3. Tambov State Technical University
4. Skolkovo Institute of Science and Technology
Issue: Vol 508, No 1 (2023)
Pages: 26-34
Section: CHEMISTRY
URL: https://rjpbr.com/2686-9535/article/view/651989
DOI: https://doi.org/10.31857/S268695352260074X
EDN: https://elibrary.ru/EWASMU
ID: 651989

Cite item

Full Text

Open Access
Restricted Access

Access granted
Restricted Access

Subscription or Fee Access

Abstract
About the authors
References
Supplementary files
Statistics

Abstract

The paper presents a comparative study of the characteristics of lithium iron phosphate positive electrodes with various types of commercially available carbon nanotubes – single-walled (SWCNT), double-walled (DWCNT) and multi-walled (MWCNT). Electrochemical characteristics of the cathode materials were investigated using electrochemical impedance spectroscopy and galvanostatic charge/discharge measurements. Cyclic stability at various current densities was estimated. The best electrochemical characteristics are exhibited by cathode materials with SWCNT (advantage over DWCNT at discharge rates higher than 10C) and DWCNT (advantage over SWCNT during prolonged cycling). During cycling at a current density of 1C, the greatest loss of capacity was demonstrated by the MWCNT-based electrode. At the same time, the electrodes with SWCNT and DWCNT demonstrated satisfactory capacity retention after 50 charge/discharge cycles: over 94 and over 98%, respectively.

Keywords

lithium-ion battery, conductive additive, carbon nanotubes, electrical conductivity

References

Natarajan S., Aravindan V. // ACS Energy Lett. 2018. V. 3. № 9. P. 2101–2103. https://doi.org/10.1021/acsenergylett.8b01233
Heidari E.K., Kamyabi-Gol A., Sohi M.H., Ataie A. // J. Ultrafine Grained Nanostruct. Mater. 2018. V. 51. № 1. P. 1–12. https://doi.org/10.22059/JUFGNSM.2018.01.01
Satyavani T.V.S.L, Ramya Kiran B., Rajesh Kumar V., Srinivas Kumar A., Naidu S.V. // Eng. Sci. Technol., Int. J. 2016. V. 19. № 1. P. 40–44. https://doi.org/10.1016/j.jestch.2015.05.011
Shih J., Lin G., James Li Y., Tai-Feng Hung, Rajan J., Karuppiah C., Chun-Chen Y. // Electrochim. Acta. 2022. V. 419. 140356. https://doi.org/10.1016/j.electacta.2022.140356
Rajoba S.J., Jadhav L.D., Patil P.S., Tyagi D.K., Varma S., Wani B.N. // J. Electron. Mater. 2017. V. 46. P. 1683–1691. https://doi.org/10.1007/s11664-016-5212-z
Zhou X., Wang F., Zhu Y., Liu Z. // J. Mater. Chem. 2011. V. 21. P. 3353–3358. https://doi.org/10.1039/C0JM03287E
Liu T., Sun S., Zhao Z., Li X., Sun X., Cao F., Wu J. // RSC Adv. 2017. V. 7. P. 20882–20887. https://doi.org/10.1039/C7RA02155K
Qi X., Blizanac B., DuPasquier A., Miodrag Ol., Li J., Winter M. // Carbon. 2013. V. 64. P. 334–340. https://doi.org/10.1016/j.carbon.2013.07.083
Ji X., Mu Y., Liang J., Jiang T., Zeng J., Lin Z., Lin Y., Yu J. // Carbon. 2021. V. 176. P. 21–30. https://doi.org/10.1016/j.carbon.2021.01.128
Juarez-Yescas C., Ramos-Sánchez G., González I. // J. Solid State Electrochem. 2018. V. 22. P. 3225–3233. https://doi.org/10.1007/s10008-018-4021-0
Chen Y., Zhang H., Chen Y., Qin G., Lei X., Liu L. // Mater. Sci. Forum. 2018. V. 913. P. 818–830. https://doi.org/10.4028/www.scientific.net/msf.913.818
Fiyadh S.S., AlSaadi M.A., Jaafar W.Z., AlOmar M.Kh., Fayaed S.S., Mohd N.S., Hin L.S., El-Shafie A. // J. Cleaner Prod. 2019. V. 230. P. 783–793. https://doi.org/10.1016/j.jclepro.2019.05.154
Zhang R., Zhang Y., Zhang Q., Xie H., Qian W., Wei F. // ACS Nano. 2013.V. 7. № 7. P. 6156–6161. https://doi.org/10.1021/nn401995z
Garg A., Chalak H.D., Belarbi M-O., Zenkour A.M., Sahoo R. // Compos. Struct. 2021. V. 272 P. 114234. https://doi.org/10.1016/j.compstruct.2021.114234
Zhang S., Hao A., Nguyen N., Oluwalowo A., Liu Z., Dessureault Y., Gyu J.P., Liang R. // Carbon. 2019. V. 144. P. 628–638. https://doi.org/10.1016/j.carbon.2018.12.091
Li J., Ma P., Chow W., To C., Tang B. Kim J.-K. // Adv. Funct. Mater. 2007. V. 17. P. 3207–3215. https://doi.org/10.1002/adfm.200700065
Wang K., Wu Y., Luo S., He X., Wang J., Jiang K., Fan S. // J. Power Sources. 2013. V. 233. P. 209–215. https://doi.org/10.1016/j.jpowsour.2013.01.102
Belharouak I., Johnson C., Amine K. // Electrochem. Commun. 2005. V. 7. № 10. P. 983–988. https://doi.org/10.1016/j.elecom.2005.06.019
Filimonenkov I.S., Urvanov S.A., Zhukova E.A., Karae-va A.R., Skryleva E.A., Mordkovich V.Z., Tsirlina G.A. // J. Electroanal. Chem. 2018. V. 827. P. 58–63. https://doi.org/10.1016/j.jelechem.2018.09.004
Filimonenkov I.S., Urvanov S.A., Kazennov N.V., Tarelkin S.A., Tsirlina G.A., Mordkovich V.Z. // J. Appl. Electrochem. 2022. V. 52. P. 487–498. https://doi.org/10.1007/s10800-021-01652-z
Meddings N., Heinrich M., Overney F., Lee J.S., Ruiz V., Napolitano E., Seitz S., Hinds G., Raccichini R., Gaberšček M., Park J. // J. Power Sources. 2020. V. 480. P. 228742. https://doi.org/10.1016/j.jpowsour.2020.228742
Zhao N., Zhi X., Wang L., Liu Y., Liang G. // J. Alloys Compd. 2015. V. 645. P. 301–308. https://doi.org/10.1016/j.jallcom.2015.05.097
Jin B., Gu H.B., Zhang W., Park K.H., Sun G. // J. Solid State Electrochem. 2008. V. 12. P. 1549–1554. https://doi.org/10.1007/s10008-008-0509-3
Wei X., Guan Y., Zheng X., Zhu Q., Shen J., Qiao N., Zhou S., Xu B. // Appl. Surf. Sci. 2018, V. 440. P. 748–754. https://doi.org/10.1016/j.apsusc.2018.01.201
Tian R., Alcala N., O’Neill S.J., Horvath D.V., Coelho J., Griffin A.J., Zhang Y., Nicolosi V., O`Dwyer C., Cole-man J.N. // ACS Appl. Energy Mater. 2020. V. 3. № 3. P. 2966–2974. https://doi.org/10.1021/acsaem.0c00034
Dreyer W., Jamnik J., Guhlke C., Huth R., Moskon J., Gaberscer M. // Nat. Mater. 2010. V. 9. P. 448–453. https://doi.org/10.1038/nmat2730
Fu Y., Wei Q., Zhang G., Zhong Y., Moghimian N., Tong X., Sun S. // Materials. 2019. V. 12. P. 842. https://doi.org/10.3390/ma12060842
Zeng H., Ji X., Tsai F., Zhang Q., Jiang T., Li R. K.Y., Shi H., Luan S., Shi D. // Solid State Ionics. 2018. V. 320. P. 92–99. https://doi.org/10.1016/j.ssi.2018.02.040
Li J., Ma P., Chow W., To C., Tang B., Kim J.-K. // Adv. Funct. Mater. 2007. V.17. P. 3207–3215. https://doi.org/10.1002/adfm.200700065
Liu X-M., Huang D.Z., Oh S.-W., Zhang B., Ma P.-C., Yuen M.M.F., Kim J.‑K. // Compos. Sci. Technol. 2012. V. 72. № 2. P. 121–144. https://doi.org/10.1016/j.compscitech.2011.11.019
Napolskiy F., Avdeev M., Yerdauletov M., Ivankov O., Bocharova S., Ryzhenkova S., Kaparova B., Mirono-vich K., Burlyaev D., Krivchenko V. // Energy Technol. 2020. V. 8. № 6. P. 2000146. https://doi.org/10.1002/ente.202000146
Yoo J.-K., Oh Y., Park T., Lee K.E., Um M.-K., Yi J.-W. // Energy Technol. 2019. V. 7. № 5. 1800845. https://doi.org/10.1002/ente.201800845