Interaction of 1,2,4-triazine-5-carbonitriles with 5-hydroxyethylsulfanyl- and 5-hydroxyethoxyethylsulfanyl-3-amino-1,2,4-triazoles

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Resumo

The solvent-free interaction of 1,2,4-triazine-5-carbonitriles with first synthesized 5-hydroxyethylsulfanyland 5-hydroxyethoxyethylsulfanyl-3-amino-1,2,4-triazoles at heating has been studied. It was shown that the presence of these substituents at the C5 position of 1,2,4-triazole changes the direction of the reaction, and 5-amino-1,2,4-triazines are formed as the main products, while the products of the ipso -substitution of the C5-cyano group containing the moiety of the substituted 1,2,4-triazole were isolated only as by-products. In the case of using 1,2,4-triazole with a fragment of monoethylene glycol at C5 position of triazine, the formation of a complex mixture of products occurred.

Sobre autores

A. Krinochkin

The Ural Federal University named after the first President of Russia B.N. Yeltsin;Postovsky Institute of Organic Synthesis, UB, RAS

E. Ladin

The Ural Federal University named after the first President of Russia B.N. Yeltsin;Postovsky Institute of Organic Synthesis, UB, RAS

Ya. Shtaitz

The Ural Federal University named after the first President of Russia B.N. Yeltsin

E. Kudryashova

The Ural Federal University named after the first President of Russia B.N. Yeltsin

D. Kopchuk

The Ural Federal University named after the first President of Russia B.N. Yeltsin;Postovsky Institute of Organic Synthesis, UB, RAS

E. Gorbunov

The Ural Federal University named after the first President of Russia B.N. Yeltsin;Postovsky Institute of Organic Synthesis, UB, RAS

Yu. Shafran

The Ural Federal University named after the first President of Russia B.N. Yeltsin

G. Zyryanov

The Ural Federal University named after the first President of Russia B.N. Yeltsin;Postovsky Institute of Organic Synthesis, UB, RAS

Email: gvzyryanov@gmail.com

V. Rusinov

The Ural Federal University named after the first President of Russia B.N. Yeltsin;Postovsky Institute of Organic Synthesis, UB, RAS

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