Bromoantimonates(III) vs. Bromobismuthates(III): Differences in the Tendency for the Formation of Polynuclear Complexes

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Pyridine-based Sb(III) bromide complexes with doubly charged cations, (PyC3)3[Sb2Br9]2 (I), (PyC4)[Sb2Br8] (II), (PyC5)2[α-Sb4Br16] (III), (PyC6)2[Sb2Br10] (IV), (4-MePyC2)2[Sb2Br10] (V), (4‑MePyC3)2[α-Sb4Br16] (VI), and (4-MePyC5)2[α-Sb4Br16] (VII), were synthesized and characterized by X-ray diffraction (CCDC nos. 2204718–2204724). The structures of these compounds were compared with the structures of related bromobismuthates(III).

作者简介

A. Usoltsev

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: adonin@niic.nsc.ru
Россия, Новосибирск

I. Korol’kov

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Email: adonin@niic.nsc.ru
Россия, Новосибирск

S. Adonin

Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

编辑信件的主要联系方式.
Email: adonin@niic.nsc.ru
Россия, Новосибирск

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