Structure and stability of group 13/15 hydrides stabilized by Lewis acids and Lewis bases

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详细

Structural and thermodynamic characteristics of donor-acceptor complexes LA·E′H2EH2·LB(E = B, Al, Ga; E′ = P, As, Sb; LB = SMe2, NMe3);LA- Lewis acids of group 13 elements ER3 (E = B, Al, Ga; R = H, Me, F, Cl, Br, I, C6F5) and transition metal carbonyls Fe(CO)4, M(CO)5, (M = Cr, Mo, W), CpMn(CO)2 were computed by quantum chemical B3LYP-D3/def2-TZVP method. It is shown that removal of the Lewis base is less endothermic than removal of Lewis acid. Stability trends of the complexes depending on group 13/15 elements and Lewis acids were established. Tungsten pentacarbonyl has the highest stabilization effect.

作者简介

A. Pomogaeva

St. Petersburg State University

A. Lisovenko

St. Petersburg State University

A. Timoshkin

St. Petersburg State University

Email: a.y.timoshkin@spbu.ru

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