Synthesis and extraction ability of amide derivatives of calix[4]resorcinarene and 1,1′-dinaphthylmethane toward metal cations

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Аннотация

Aminolysis of ester derivatives of 1,1′-dinaphthylmethane and rctt -calix[4]resorcinarene afforded a series of ligands, which differ in molecular platform structure, the number of electron-donating sites, the nature of terminal amide component, the nature and size of the spacers connecting the polycyclic core with amide group. Using liquid extraction method, the effect of ligand structural features on its ability to recognize and bind s -, p -, d -, f -metal cations was investigated, and the stoichiometry of formed complexes was calculated.

Авторлар туралы

V. Glushko

Institute of Biology and Chemistry, Moscow Pedagogical State University

O. Serkova

Institute of Biology and Chemistry, Moscow Pedagogical State University

Email: os.serkova@mpgu.su

A. Kamkina

Institute of Biology and Chemistry, Moscow Pedagogical State University

S. Isaeva

Institute of Biology and Chemistry, Moscow Pedagogical State University

I. Toropygin

Institute of Biomedical Chemistry

V. Maslennikova

Institute of Biology and Chemistry, Moscow Pedagogical State University

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