Extraction of REE(III) with Mixtures of 2,4,6-tris(Diarylphosphoryl)-1,3,5-triazines and Picrolonic Acid

A. N. Turanov; Туранов А. Н.; V. K. Karandashev; Карандашев В. К.; O. I. Artyushin; Артюшин О. И.; E. V. Smirnova; Смирнова Е. В.; G. V. Bodrin; Бодрин Г. В.; V. K. Brel; Брель В. К.

doi:10.31857/S0044457X22602139

Extraction of REE(III) with Mixtures of 2,4,6-tris(Diarylphosphoryl)-1,3,5-triazines and Picrolonic Acid

Autores: Turanov A.N.¹, Karandashev V.K.², Artyushin O.I.³, Smirnova E.V.³, Bodrin G.V.³, Brel V.K.³
Afiliações:
1. Yu.A. Osipyan Institute of Solid State Physics, Russian Academy of Sciences
2. Institute of Microelectronics Technology and High Purity Materials, Russian Academy of Sciences
3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Edição: Volume 68, Nº 5 (2023)
Páginas: 664-671
Seção: ФИЗИКОХИМИЯ РАСТВОРОВ
URL: https://rjpbr.com/0044-457X/article/view/665261
DOI: https://doi.org/10.31857/S0044457X22602139
EDN: https://elibrary.ru/SNIRMA
ID: 665261

Citar

Texto integral

Acesso aberto
Acesso é fechado

Acesso está concedido
Acesso é fechado

Acesso é pago ou somente para assinantes

Resumo
Sobre autores
Bibliografia
Arquivos suplementares
Estatísticas

Resumo

Considerable synergetic effect has been revealed on extraction of REE(III) ions from chloride solutions with mixtures of picrolonic acid and tris(diarylphosphoryl)-1,3,5-triazines in 1,2-dichloroethane due to formation of hydrophobic mixed-ligand REE(III) complexes. Parameters of extraction equilibrium and stoichiometry of resulting complexes have been determined. Effect of aqueous phase composition, organic solvent nature, and extractant structure has been studied. The largest synergetic effect has been observed in the system with tris(ditolylphosphoryl)-1,3,5-triazine.

Palavras-chave

REE(III), extraction, picrolonic acid, tris(diarylphosphoryl)-1,3,5-triazines, synergism

Bibliografia

Neves H.P., Ferreira G.M.D., Ferreira G.M.D. et al. // Sep. Pur. Technol. 2022. V. 282. 120064. https://doi.org/10.1016/j.seppur.2021.120064
Zhou B.L., Li Z.X., Chen C.C. // Minerals. 2017. V. 7. P. 203. https://doi.org/10.3390/min7110203
Moalla R., Gargouri M., Khmiri F. et al. // Environ. Eng. Res. 2018. V. 23. P. 36. https://doi.org/10.4491/eer.2017.055
Liu T., Chen J. // Sep. Pur. Technol. 2021. V. 276. 119263. https://doi.org/10.1016/j.seppur.2021.119263
Li D. // J. Rare Earths. 2019. V. 37. P. 468. https://doi.org/10.1016/j.jre.2018.07.016
Soukeur A., Szymczyk A., Berbar Y. et al. // Sep. Pur. Technol. 2021. V. 256. 117857. https://doi.org/10.1016/j.seppur.2020.117857
Leoncini A., Huskens J., Verboom W. // Chem. Soc. Rev. 2017. V. 46. № 23. P. 7229. https://doi.org/10.1039/C7CS00574A
Сафиулина А.М., Борисова Н.Е., Лизунов А.В. и др. // Журн. неорган. химии. 2022. Т. 67. С. 513.
Matveev P.I., Borisova N.E., Andreadi N.G. et al. // Dalton Trans. 2019. V. 48. P. 2554. https://doi.org/10.1039/C8DT04729D
Artyushin O.I., Vologzhanina A.V., Turanov A.N. et al. // Mendeleev Commun. 2021. V. 31. P. 306. https://doi.org/10.1016/j.mencom.2021.04.009
Smirnova E.V., Artyushin O.I., Vologzhanina A.V. et al. // Mendeleev Commun. 2022. V. 32. P. 664. https://doi.org/10.1016/j.mencom.2022.09.032
Чмутова М.К., Матросов Е.И., Иванова Л.А. и др. // Радиохимия. 1993. Т. 35. № 1. С. 70.
Bond A.H., Dietz M.L., Chiarizia R. // Ind. Eng. Chem. Res. 2000. V. 39. P. 3442. https://doi.org/10.1021/ie000356j
Atanassova M., Kurteva V. // RSC Advances. 2016. V. 6. P. 11303. https://doi.org/10.1039/C5RA22306G
Золотов Ю.А., Кузьмин Н.М. Экстракция металлов ацилпиразолонами. М.: Наука, 1977. 140 с.
Ali A. // Radiochim. Acta. 2004. V. 92. P. 925.
Habib-ur-Rehman, Ali A., Waquar F. // J. Radioanal. Nucl. Chem. 2015. V. 303. P. 139. https://doi.org/10.1007/s10967-014-3440-3
Туранов А.Н., Карандашев В.К., Шарова Е.В. и др. // Радиохимия. 2013. Т. 55. № 2. С. 156.
Turanov A.N., Karandashev V.K. // Solv. Extr. Ion Exch. 2017. V. 35. P. 104. https://doi.org/10.1080/07366299.2017.1288044
Туранов А.Н., Карандашев В.К., Харламов А.В. и др. // Журн. неорган. химии. 2018. Т. 63. С. 1652.
Туранов А.Н., Карандашев В.К., Артюшин О.И. и др. // Журн. общ. химии. 2022. Т. 92. № 8. С. 1289.
Hewertson W., Shaw R.A., Smith B.C. // J. Chem. Soc. 1963. P. 1670.
Osman M.M., Abou Ali S.A., Ali G.A. // Pak. J. Sci. Ind. Res. 1984. V. 276. P. 85.
Nash K.L., Jensen M.P. // Sep. Sci. Technol. 2001. V. 36. № 5–6. P. 1257. https://doi.org/10.1081/SS-100103649
Розен А.М., Крупнов Б.В. // Успехи химии. 1996. Т. 65. № 11. С. 1052.