Hot Isostatic Pressing-Induced Structural Changes in MgAl2O4 Ceramics

A. A. Dunaev; Дунаев А. А.; S. B. Eron’ko; Еронько С. Б.; B. A. Ignatenkov; Игнатенков Б. А.; A. I. Markova; Маркова А. И.; M. V. Narykova; Нарыкова М. В.; P. M. Pakhomov; Пахомов П. М.; S. D. Khizhnyak; Хижняк С. Д.; A. E. Chmel’; Чмель А. Е.

doi:10.31857/S0002337X23050032

Hot Isostatic Pressing-Induced Structural Changes in MgAl2O4 Ceramics

Autores: Dunaev A.A.¹, Eron’ko S.B.¹, Ignatenkov B.A.¹, Markova A.I.², Narykova M.V.³, Pakhomov P.M.², Khizhnyak S.D.², Chmel’ A.E.³
Afiliações:
1. Vavilov State Optical Institute
2. Tver State University
3. Ioffe Institute
Edição: Volume 59, Nº 5 (2023)
Páginas: 548-551
Seção: Articles
URL: https://rjpbr.com/0002-337X/article/view/668263
DOI: https://doi.org/10.31857/S0002337X23050032
EDN: https://elibrary.ru/QGHJJD
ID: 668263

Citar

Texto integral

Acesso aberto
Acesso é fechado

Acesso está concedido
Acesso é fechado

Acesso é pago ou somente para assinantes

Resumo
Sobre autores
Bibliografia
Arquivos suplementares
Estatísticas

Resumo

Magnesium aluminate spinel (MgAl2O4) ceramics have been subjected to hot isostatic pressing. The process led to a 0.28% increase in the density of the ceramics compared to samples prepared by primary hot pressing. IR spectroscopy has been used to evaluate structural changes in the densified material. In the IR reflection spectrum measured from 40 to 1000 cm–1, the increase in density showed up as a decrease in the intensity of some bands due to isolated vibrational modes in the MgO4 and AlO4 tetrahedra. The effect was attributed to vibrational mode mixing in the tetrahedral structural units in the densified ceramics. This finding indicates that consolidation of the material is accompanied by an increase in the inner connectivity of crystallites. At the same time, the frequency and intensity of the stretching modes of the Al–O groups in the AlO6 octahedra remained unchanged after isostatic pressing, suggesting that the heat treatment caused no stoichiometric distortion.

Palavras-chave

ceramics, magnesium aluminate spinel, hot isostatic pressing, IR spectroscopy

Bibliografia

Ganesh I. A Review On Magnesium Aluminate (MgAl2O4) Spinel: Synthesis, Processing and Applications // Int. Mater. Rev. 2013. V. 58. № 2. P. 63–112. https://doi.org/10.1179/1743280412Y.0000000001
Габелков С.В., Тарасов Р.В., Полтавцев Н.С., Курило Ю.П., Старолат М.П., Андриевская Н.Ф., Миронова А.Г., Дедовская Е.Г., Дитвиненко Л.М., Белкин Ф.В. Фазовые превращения при низкотемпературном синтезе MgAl2О4 // Неорган. материалы. 2007. Т. 43. № 4. С. 462–470.
Garner F.A., Hollenberg G.W., Hoobs F.D., Ryan J.L., Li Z., Black C.A., Bradt R.C. Dimension Stability, Optical and Elastic Properties of MgAl2O4 Spinel Irradiated in FFTF to Very High Exposures // J. Nucl. Mater. 1994. V. 212–215. P. 1087–1090. https://doi.org/0.1016/0022-3115(94)91000-6
Sokol M., Ratzker B., Kalabukhov S., Dariel M.P., Galun E., Frage N. Transparent Polycrystalline Magnesium Aluminate Spinel Fabricated By Spark Plasma Sintering // Adv. Mater. 2018. V. 30. P. 1706283. https://doi.org/10.1002/adma.201706283
Gajdowski K., Böhmler J., Lorgouilloux Y., Lemonnier S., d’Astorg S., Barraud E., Leriche A. Influence of Post-HIP Temperature on Microstructural and Optical Properties of Pure MgAl2O4 Spinel: From Opaque to Transparent Ceramics // J. Eur. Ceram. Soc. 2017. V. 37. P. 5347–5351. https://doi.org/10.1016/j.jeurceramsoc.2017.07.031
Tsai D.S., Wang C.T., Yang S.J. Hot Isostatic Pressing of MgAl2O4 Spinel Infrared Windows // Mater. Manuf. Processes. 1994. V. 9. P. 709–719. https://doi.org/10.1080/10426919408934941
Shi Zh., Zhao Q., Guo B., Ji T., Wang H. A Review on Processing Polycrystalline Magnesium Aluminate Spinel (MgAl2O4): Sintering Techniques, Material Properties and Machinability // Mater. Design. 2020. V. 193. P. 10858. https://doi.org/10.1016/j.matdes.2020.108858
Gilde G., Patel P., Patterson P., Blodgett D., Duncan D., Hahn D. Valuation of Hot Pressing and Hot Isostatic Pressing Parameters on The Optical Properties of Spinel // J. Am. Ceram. Soc. 2005. V. 88. P. 2747–2751. https://doi.org/10.1111/j.1551-2916.2005.00527.x
Толстикова Д.В., Михайлов М.Д., Смирнов В.М. Особенности синтеза наночастиц алюмомагниевой шпинели в расплаве хлорида калия // Журн. общ. химии. 2014. Т. 84. № 10. С. 1744–1745.
Chmel A., Eronko S.B., Kondyrev A.M., Nazarova V.Ya. Optical Resistance of Sapphire // J. Mater. Sci. 1993. V. 28. P. 4673–4680. https://doi.org/10.1007/BF00414257
Barker A.S. Infrared Lattice Vibrations and Dielectric Dispersion in Corundum // Phys. Rev. 1963. V. 132. P. 1474–1481. https://doi.org/10.1103/PhysRev.132.1474
Петрик В.И. Броневые оптические материалы. Шпинель. Иркутск: Областная типография № 1. 2011. С. 335.
Slotznick S.P., Shim S.-H. In Situ Raman Spectroscopy Measurements of MgAl2O4 Spinel Up to 1400°C // Am. Mineral. 2008. V. 93. P. 470–476. https://doi.org/10.2138/am.2008.2687
Fu P., Lu W. Lei W. Wu K., Xu Y., Wu J. Thermal Stability and Microstructure Characterization of MgAl2O4 Nanoparticles Synthesized by Reverse Microemulsion Method // Mater. Res. 2013. V. 16. P. 844–849. https://doi.org/10.1590/S1516-14392013005000062
Ahmad S.M., Hussain T., Ahmad R., Siddiqui J., Ali D. Synthesis and Characterization of Magnesium Aluminate (MgAl2O4) Spinel (MAS) Thin Films // Mater. Res. Express. 2018. V. 5. P. 016415. https://doi.org/10.1088/2053-1591/aaa828
Radishevskaya N.I., Nazarova A.Yu., Lvov O.V., Kasatsky N.G., Kitler V.D. Synthesis of Magnesium Aluminate Spinel in the MgO–Al2O3–Al System Using the SHS Method // J. Phys.: Conf. Ser. 2019. V. 1214. P. 012019. https://doi.org/10.1088/1742-6596/1214/1/012019
Radishevskaya N., Lepakova O., Karakchieva N., Nazarova A., Afanasiev N., Godymchuk A., Gusev A. Self-Propagating High Temperature Synthesis of TiB2–MgAl2O4 // Comp. Met. 2017. № 295. P. 1–7. https://doi.org/10.3390/met7080295
Pei L.Zh., Yin W.Y., Wang J.F., Chen J., Fan Ch.G., Zhang Q.F. Low Temperature Synthesis of Magnesium Oxide and Spinel Powders by a Sol-Gel Process // Mater. Res. 2010. V. 13. P. 339–343. https://doi.org/10.1590/S1516-4392010000300010
Nassar M.Y., Ahmed I.S., Samir I. A Novel Synthetic Route for Magnesium Aluminate (MgAl2O4) Nanoparticles Using Sol–Gel Auto Combustion Method and Their Photocatalytic Properties // Spectrochim. Acta, Part A. 2014. V. 131. P. 329–334. https://doi.org/10.1016/j.saa.2014.04.040